How does strength of boric acid solution increase in presence of salicylic acid?












7












$begingroup$


A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.



To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.



But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.






inorganic-chemistry acid-base







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  • $begingroup$
    see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
    $endgroup$
    – MaxW
    17 hours ago
















7












$begingroup$


A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.



To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.



But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.






inorganic-chemistry acid-base







share|improve this question









New contributor




Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.







$endgroup$












  • $begingroup$
    see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
    $endgroup$
    – MaxW
    17 hours ago














7












7








7





$begingroup$


A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.



To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.



But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.






inorganic-chemistry acid-base







share|improve this question









New contributor




Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.







$endgroup$




A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.



To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.



But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.






inorganic-chemistry acid-base




inorganic-chemistry acid-base






share|improve this question









New contributor




Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.











share|improve this question









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edited 15 hours ago









andselisk

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asked 18 hours ago









RicheekRicheek

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Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
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  • $begingroup$
    see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
    $endgroup$
    – MaxW
    17 hours ago


















  • $begingroup$
    see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
    $endgroup$
    – MaxW
    17 hours ago
















$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
17 hours ago




$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
17 hours ago










2 Answers
2






active

oldest

votes


















12












$begingroup$

boric acid and salicylic acid



Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421






share|improve this answer











$endgroup$





















    2












    $begingroup$

    By googling "boric acid salicylic acid"
    I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



    https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421






    share|improve this answer









    $endgroup$














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      2 Answers
      2






      active

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      2 Answers
      2






      active

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      active

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      12












      $begingroup$

      boric acid and salicylic acid



      Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




      References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421






      share|improve this answer











      $endgroup$


















        12












        $begingroup$

        boric acid and salicylic acid



        Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




        References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421






        share|improve this answer











        $endgroup$
















          12












          12








          12





          $begingroup$

          boric acid and salicylic acid



          Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




          References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421






          share|improve this answer











          $endgroup$



          boric acid and salicylic acid



          Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.




          References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421







          share|improve this answer














          share|improve this answer



          share|improve this answer








          edited 15 hours ago

























          answered 17 hours ago









          William R. EbenezerWilliam R. Ebenezer

          64914




          64914























              2












              $begingroup$

              By googling "boric acid salicylic acid"
              I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



              https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421






              share|improve this answer









              $endgroup$


















                2












                $begingroup$

                By googling "boric acid salicylic acid"
                I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



                https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421






                share|improve this answer









                $endgroup$
















                  2












                  2








                  2





                  $begingroup$

                  By googling "boric acid salicylic acid"
                  I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



                  https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421






                  share|improve this answer









                  $endgroup$



                  By googling "boric acid salicylic acid"
                  I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.



                  https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421







                  share|improve this answer












                  share|improve this answer



                  share|improve this answer










                  answered 17 hours ago









                  PoutnikPoutnik

                  73928




                  73928






















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