Is the differential, dp, exact or not?
$begingroup$
Consider the differential $$mathrm dp=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV$$ (where $a$ is a constant value)
(a) Determine whether the above differential, i.e. $mathrm dp$, is exact or not. Show all your steps and evaluation of the appropriate partial differentials!
I have no idea on how to even start this. As far as I can tell the differential is exact, but I don't know how to prove or show it. I'm really struggling to show the steps involved. I would appreciate any advice and thank you very much in advance.
thermodynamics
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add a comment |
$begingroup$
Consider the differential $$mathrm dp=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV$$ (where $a$ is a constant value)
(a) Determine whether the above differential, i.e. $mathrm dp$, is exact or not. Show all your steps and evaluation of the appropriate partial differentials!
I have no idea on how to even start this. As far as I can tell the differential is exact, but I don't know how to prove or show it. I'm really struggling to show the steps involved. I would appreciate any advice and thank you very much in advance.
thermodynamics
$endgroup$
$begingroup$
I'm voting to close this question as off-topic because it is a mathmatics question.
$endgroup$
– A.K.
yesterday
10
$begingroup$
Not all chemistry is done in a vial.
$endgroup$
– Charlie Crown
21 hours ago
add a comment |
$begingroup$
Consider the differential $$mathrm dp=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV$$ (where $a$ is a constant value)
(a) Determine whether the above differential, i.e. $mathrm dp$, is exact or not. Show all your steps and evaluation of the appropriate partial differentials!
I have no idea on how to even start this. As far as I can tell the differential is exact, but I don't know how to prove or show it. I'm really struggling to show the steps involved. I would appreciate any advice and thank you very much in advance.
thermodynamics
$endgroup$
Consider the differential $$mathrm dp=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV$$ (where $a$ is a constant value)
(a) Determine whether the above differential, i.e. $mathrm dp$, is exact or not. Show all your steps and evaluation of the appropriate partial differentials!
I have no idea on how to even start this. As far as I can tell the differential is exact, but I don't know how to prove or show it. I'm really struggling to show the steps involved. I would appreciate any advice and thank you very much in advance.
thermodynamics
thermodynamics
edited yesterday
Charlie Crown
418115
418115
asked yesterday
NicciNicci
602
602
$begingroup$
I'm voting to close this question as off-topic because it is a mathmatics question.
$endgroup$
– A.K.
yesterday
10
$begingroup$
Not all chemistry is done in a vial.
$endgroup$
– Charlie Crown
21 hours ago
add a comment |
$begingroup$
I'm voting to close this question as off-topic because it is a mathmatics question.
$endgroup$
– A.K.
yesterday
10
$begingroup$
Not all chemistry is done in a vial.
$endgroup$
– Charlie Crown
21 hours ago
$begingroup$
I'm voting to close this question as off-topic because it is a mathmatics question.
$endgroup$
– A.K.
yesterday
$begingroup$
I'm voting to close this question as off-topic because it is a mathmatics question.
$endgroup$
– A.K.
yesterday
10
10
$begingroup$
Not all chemistry is done in a vial.
$endgroup$
– Charlie Crown
21 hours ago
$begingroup$
Not all chemistry is done in a vial.
$endgroup$
– Charlie Crown
21 hours ago
add a comment |
2 Answers
2
active
oldest
votes
$begingroup$
Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.
Let me rewrite the differential as
$$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$
where
$$A(V) = frac{R}{V}$$
and
$$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$
A differential is exact if
$$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$
Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!
Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to
$$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$
$$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$
If the two partial derivatives are the same, the differential is exact. I will let you be the judge.
$endgroup$
$begingroup$
I don't think you should basically have revealed the full solution.
$endgroup$
– Chester Miller
yesterday
1
$begingroup$
In my experience people mess up the differentiation and then think they did everything wrong
$endgroup$
– Charlie Crown
yesterday
2
$begingroup$
Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
$endgroup$
– orthocresol♦
yesterday
$begingroup$
@orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
$endgroup$
– Mithoron
yesterday
2
$begingroup$
No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
$endgroup$
– Charlie Crown
yesterday
|
show 2 more comments
$begingroup$
For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
$$
text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
$$
To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.
For the case given:
$$
mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
$$
If $mathrm dp$ is an exact differential, that would mean that:
$$
left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
$$
There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.
Integration
Taking indefinite integrals of the suspected derivatives:
$$int frac RV mathrm d T = frac{RT}{V} + g(V) \
int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
to p(T,V) = frac{RT-2a}{V} + c
$$
Differentiation
It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:
$$
frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
$$
Assuming:
$$ left(frac{partial p}{partial T}right)_{V} = frac RV \
to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
$$
Assuming
$$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
$$
Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.
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2 Answers
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oldest
votes
2 Answers
2
active
oldest
votes
active
oldest
votes
active
oldest
votes
$begingroup$
Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.
Let me rewrite the differential as
$$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$
where
$$A(V) = frac{R}{V}$$
and
$$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$
A differential is exact if
$$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$
Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!
Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to
$$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$
$$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$
If the two partial derivatives are the same, the differential is exact. I will let you be the judge.
$endgroup$
$begingroup$
I don't think you should basically have revealed the full solution.
$endgroup$
– Chester Miller
yesterday
1
$begingroup$
In my experience people mess up the differentiation and then think they did everything wrong
$endgroup$
– Charlie Crown
yesterday
2
$begingroup$
Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
$endgroup$
– orthocresol♦
yesterday
$begingroup$
@orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
$endgroup$
– Mithoron
yesterday
2
$begingroup$
No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
$endgroup$
– Charlie Crown
yesterday
|
show 2 more comments
$begingroup$
Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.
Let me rewrite the differential as
$$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$
where
$$A(V) = frac{R}{V}$$
and
$$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$
A differential is exact if
$$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$
Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!
Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to
$$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$
$$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$
If the two partial derivatives are the same, the differential is exact. I will let you be the judge.
$endgroup$
$begingroup$
I don't think you should basically have revealed the full solution.
$endgroup$
– Chester Miller
yesterday
1
$begingroup$
In my experience people mess up the differentiation and then think they did everything wrong
$endgroup$
– Charlie Crown
yesterday
2
$begingroup$
Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
$endgroup$
– orthocresol♦
yesterday
$begingroup$
@orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
$endgroup$
– Mithoron
yesterday
2
$begingroup$
No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
$endgroup$
– Charlie Crown
yesterday
|
show 2 more comments
$begingroup$
Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.
Let me rewrite the differential as
$$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$
where
$$A(V) = frac{R}{V}$$
and
$$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$
A differential is exact if
$$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$
Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!
Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to
$$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$
$$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$
If the two partial derivatives are the same, the differential is exact. I will let you be the judge.
$endgroup$
Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.
Let me rewrite the differential as
$$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$
where
$$A(V) = frac{R}{V}$$
and
$$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$
A differential is exact if
$$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$
Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!
Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to
$$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$
$$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$
If the two partial derivatives are the same, the differential is exact. I will let you be the judge.
edited 5 hours ago
Loong♦
33.7k884175
33.7k884175
answered yesterday
Charlie CrownCharlie Crown
418115
418115
$begingroup$
I don't think you should basically have revealed the full solution.
$endgroup$
– Chester Miller
yesterday
1
$begingroup$
In my experience people mess up the differentiation and then think they did everything wrong
$endgroup$
– Charlie Crown
yesterday
2
$begingroup$
Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
$endgroup$
– orthocresol♦
yesterday
$begingroup$
@orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
$endgroup$
– Mithoron
yesterday
2
$begingroup$
No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
$endgroup$
– Charlie Crown
yesterday
|
show 2 more comments
$begingroup$
I don't think you should basically have revealed the full solution.
$endgroup$
– Chester Miller
yesterday
1
$begingroup$
In my experience people mess up the differentiation and then think they did everything wrong
$endgroup$
– Charlie Crown
yesterday
2
$begingroup$
Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
$endgroup$
– orthocresol♦
yesterday
$begingroup$
@orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
$endgroup$
– Mithoron
yesterday
2
$begingroup$
No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
$endgroup$
– Charlie Crown
yesterday
$begingroup$
I don't think you should basically have revealed the full solution.
$endgroup$
– Chester Miller
yesterday
$begingroup$
I don't think you should basically have revealed the full solution.
$endgroup$
– Chester Miller
yesterday
1
1
$begingroup$
In my experience people mess up the differentiation and then think they did everything wrong
$endgroup$
– Charlie Crown
yesterday
$begingroup$
In my experience people mess up the differentiation and then think they did everything wrong
$endgroup$
– Charlie Crown
yesterday
2
2
$begingroup$
Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
$endgroup$
– orthocresol♦
yesterday
$begingroup$
Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
$endgroup$
– orthocresol♦
yesterday
$begingroup$
@orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
$endgroup$
– Mithoron
yesterday
$begingroup$
@orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
$endgroup$
– Mithoron
yesterday
2
2
$begingroup$
No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
$endgroup$
– Charlie Crown
yesterday
$begingroup$
No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
$endgroup$
– Charlie Crown
yesterday
|
show 2 more comments
$begingroup$
For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
$$
text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
$$
To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.
For the case given:
$$
mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
$$
If $mathrm dp$ is an exact differential, that would mean that:
$$
left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
$$
There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.
Integration
Taking indefinite integrals of the suspected derivatives:
$$int frac RV mathrm d T = frac{RT}{V} + g(V) \
int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
to p(T,V) = frac{RT-2a}{V} + c
$$
Differentiation
It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:
$$
frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
$$
Assuming:
$$ left(frac{partial p}{partial T}right)_{V} = frac RV \
to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
$$
Assuming
$$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
$$
Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.
$endgroup$
add a comment |
$begingroup$
For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
$$
text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
$$
To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.
For the case given:
$$
mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
$$
If $mathrm dp$ is an exact differential, that would mean that:
$$
left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
$$
There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.
Integration
Taking indefinite integrals of the suspected derivatives:
$$int frac RV mathrm d T = frac{RT}{V} + g(V) \
int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
to p(T,V) = frac{RT-2a}{V} + c
$$
Differentiation
It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:
$$
frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
$$
Assuming:
$$ left(frac{partial p}{partial T}right)_{V} = frac RV \
to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
$$
Assuming
$$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
$$
Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.
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For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
$$
text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
$$
To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.
For the case given:
$$
mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
$$
If $mathrm dp$ is an exact differential, that would mean that:
$$
left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
$$
There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.
Integration
Taking indefinite integrals of the suspected derivatives:
$$int frac RV mathrm d T = frac{RT}{V} + g(V) \
int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
to p(T,V) = frac{RT-2a}{V} + c
$$
Differentiation
It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:
$$
frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
$$
Assuming:
$$ left(frac{partial p}{partial T}right)_{V} = frac RV \
to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
$$
Assuming
$$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
$$
Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.
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For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
$$
text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
$$
To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.
For the case given:
$$
mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
$$
If $mathrm dp$ is an exact differential, that would mean that:
$$
left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
$$
There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.
Integration
Taking indefinite integrals of the suspected derivatives:
$$int frac RV mathrm d T = frac{RT}{V} + g(V) \
int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
to p(T,V) = frac{RT-2a}{V} + c
$$
Differentiation
It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:
$$
frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
$$
Assuming:
$$ left(frac{partial p}{partial T}right)_{V} = frac RV \
to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
$$
Assuming
$$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
$$
Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.
edited 4 hours ago
Tyberius
7,00832160
7,00832160
answered yesterday
user213305user213305
1,031416
1,031416
add a comment |
add a comment |
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I'm voting to close this question as off-topic because it is a mathmatics question.
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– A.K.
yesterday
10
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Not all chemistry is done in a vial.
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– Charlie Crown
21 hours ago