Is the differential, dp, exact or not?












6












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Consider the differential $$mathrm dp=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV$$ (where $a$ is a constant value)



(a) Determine whether the above differential, i.e. $mathrm dp$, is exact or not. Show all your steps and evaluation of the appropriate partial differentials!




I have no idea on how to even start this. As far as I can tell the differential is exact, but I don't know how to prove or show it. I'm really struggling to show the steps involved. I would appreciate any advice and thank you very much in advance.










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  • $begingroup$
    I'm voting to close this question as off-topic because it is a mathmatics question.
    $endgroup$
    – A.K.
    yesterday






  • 10




    $begingroup$
    Not all chemistry is done in a vial.
    $endgroup$
    – Charlie Crown
    21 hours ago
















6












$begingroup$



Consider the differential $$mathrm dp=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV$$ (where $a$ is a constant value)



(a) Determine whether the above differential, i.e. $mathrm dp$, is exact or not. Show all your steps and evaluation of the appropriate partial differentials!




I have no idea on how to even start this. As far as I can tell the differential is exact, but I don't know how to prove or show it. I'm really struggling to show the steps involved. I would appreciate any advice and thank you very much in advance.










share|improve this question











$endgroup$












  • $begingroup$
    I'm voting to close this question as off-topic because it is a mathmatics question.
    $endgroup$
    – A.K.
    yesterday






  • 10




    $begingroup$
    Not all chemistry is done in a vial.
    $endgroup$
    – Charlie Crown
    21 hours ago














6












6








6


2



$begingroup$



Consider the differential $$mathrm dp=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV$$ (where $a$ is a constant value)



(a) Determine whether the above differential, i.e. $mathrm dp$, is exact or not. Show all your steps and evaluation of the appropriate partial differentials!




I have no idea on how to even start this. As far as I can tell the differential is exact, but I don't know how to prove or show it. I'm really struggling to show the steps involved. I would appreciate any advice and thank you very much in advance.










share|improve this question











$endgroup$





Consider the differential $$mathrm dp=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV$$ (where $a$ is a constant value)



(a) Determine whether the above differential, i.e. $mathrm dp$, is exact or not. Show all your steps and evaluation of the appropriate partial differentials!




I have no idea on how to even start this. As far as I can tell the differential is exact, but I don't know how to prove or show it. I'm really struggling to show the steps involved. I would appreciate any advice and thank you very much in advance.







thermodynamics






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edited yesterday









Charlie Crown

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418115










asked yesterday









NicciNicci

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602












  • $begingroup$
    I'm voting to close this question as off-topic because it is a mathmatics question.
    $endgroup$
    – A.K.
    yesterday






  • 10




    $begingroup$
    Not all chemistry is done in a vial.
    $endgroup$
    – Charlie Crown
    21 hours ago


















  • $begingroup$
    I'm voting to close this question as off-topic because it is a mathmatics question.
    $endgroup$
    – A.K.
    yesterday






  • 10




    $begingroup$
    Not all chemistry is done in a vial.
    $endgroup$
    – Charlie Crown
    21 hours ago
















$begingroup$
I'm voting to close this question as off-topic because it is a mathmatics question.
$endgroup$
– A.K.
yesterday




$begingroup$
I'm voting to close this question as off-topic because it is a mathmatics question.
$endgroup$
– A.K.
yesterday




10




10




$begingroup$
Not all chemistry is done in a vial.
$endgroup$
– Charlie Crown
21 hours ago




$begingroup$
Not all chemistry is done in a vial.
$endgroup$
– Charlie Crown
21 hours ago










2 Answers
2






active

oldest

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13












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Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.



Let me rewrite the differential as



$$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$



where



$$A(V) = frac{R}{V}$$



and



$$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$



A differential is exact if



$$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$



Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!



Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to



$$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$



$$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$



If the two partial derivatives are the same, the differential is exact. I will let you be the judge.






share|improve this answer











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  • $begingroup$
    I don't think you should basically have revealed the full solution.
    $endgroup$
    – Chester Miller
    yesterday






  • 1




    $begingroup$
    In my experience people mess up the differentiation and then think they did everything wrong
    $endgroup$
    – Charlie Crown
    yesterday






  • 2




    $begingroup$
    Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
    $endgroup$
    – orthocresol
    yesterday












  • $begingroup$
    @orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
    $endgroup$
    – Mithoron
    yesterday






  • 2




    $begingroup$
    No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
    $endgroup$
    – Charlie Crown
    yesterday



















7












$begingroup$

For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
$$
text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
$$



To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.



For the case given:



$$
mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
$$



If $mathrm dp$ is an exact differential, that would mean that:



$$
left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
$$



There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.



Integration



Taking indefinite integrals of the suspected derivatives:



$$int frac RV mathrm d T = frac{RT}{V} + g(V) \
int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
to p(T,V) = frac{RT-2a}{V} + c
$$



Differentiation



It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:



$$
frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
$$



Assuming:
$$ left(frac{partial p}{partial T}right)_{V} = frac RV \
to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
$$



Assuming



$$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
$$



Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.






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    2 Answers
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    13












    $begingroup$

    Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.



    Let me rewrite the differential as



    $$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$



    where



    $$A(V) = frac{R}{V}$$



    and



    $$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$



    A differential is exact if



    $$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$



    Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!



    Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to



    $$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$



    $$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$



    If the two partial derivatives are the same, the differential is exact. I will let you be the judge.






    share|improve this answer











    $endgroup$













    • $begingroup$
      I don't think you should basically have revealed the full solution.
      $endgroup$
      – Chester Miller
      yesterday






    • 1




      $begingroup$
      In my experience people mess up the differentiation and then think they did everything wrong
      $endgroup$
      – Charlie Crown
      yesterday






    • 2




      $begingroup$
      Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
      $endgroup$
      – orthocresol
      yesterday












    • $begingroup$
      @orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
      $endgroup$
      – Mithoron
      yesterday






    • 2




      $begingroup$
      No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
      $endgroup$
      – Charlie Crown
      yesterday
















    13












    $begingroup$

    Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.



    Let me rewrite the differential as



    $$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$



    where



    $$A(V) = frac{R}{V}$$



    and



    $$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$



    A differential is exact if



    $$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$



    Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!



    Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to



    $$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$



    $$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$



    If the two partial derivatives are the same, the differential is exact. I will let you be the judge.






    share|improve this answer











    $endgroup$













    • $begingroup$
      I don't think you should basically have revealed the full solution.
      $endgroup$
      – Chester Miller
      yesterday






    • 1




      $begingroup$
      In my experience people mess up the differentiation and then think they did everything wrong
      $endgroup$
      – Charlie Crown
      yesterday






    • 2




      $begingroup$
      Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
      $endgroup$
      – orthocresol
      yesterday












    • $begingroup$
      @orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
      $endgroup$
      – Mithoron
      yesterday






    • 2




      $begingroup$
      No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
      $endgroup$
      – Charlie Crown
      yesterday














    13












    13








    13





    $begingroup$

    Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.



    Let me rewrite the differential as



    $$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$



    where



    $$A(V) = frac{R}{V}$$



    and



    $$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$



    A differential is exact if



    $$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$



    Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!



    Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to



    $$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$



    $$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$



    If the two partial derivatives are the same, the differential is exact. I will let you be the judge.






    share|improve this answer











    $endgroup$



    Your function $p$ is a function of the independent variables $V$ and $T$ i.e., $p(V,T)$. The other variables, $a$, and $R$ are constants.



    Let me rewrite the differential as



    $$mathrm{d}p = A(V),mathrm{d}T + B(T,V),mathrm{d}V$$



    where



    $$A(V) = frac{R}{V}$$



    and



    $$ B(T,V) = left( frac{2a}{V^3} - frac{RT}{V^2} right) $$



    A differential is exact if



    $$left( frac{partial A}{partial V} right)_T = left( frac{partial B}{partial T} right)_V $$



    Note that subscripts denote that the variable is being held constant during the partial differentiation. The problem already told us what our $A$ and $B$ terms are, and I wrote them out explicitly above. Now, we just need to take the appropriate partial differentials and compare. If they are equal, then $mathrm{d}p$ is exact!



    Writing out the formulas took awhile, it seems a shame to stop now... A little bit of differentiating, remembering to hold the appropriate variables constant during differentiation leads to



    $$left( frac{partial A}{partial V} right)_T = -frac{R}{V^2}$$



    $$left( frac{partial B}{partial T} right)_V = -frac{R}{V^2}$$



    If the two partial derivatives are the same, the differential is exact. I will let you be the judge.







    share|improve this answer














    share|improve this answer



    share|improve this answer








    edited 5 hours ago









    Loong

    33.7k884175




    33.7k884175










    answered yesterday









    Charlie CrownCharlie Crown

    418115




    418115












    • $begingroup$
      I don't think you should basically have revealed the full solution.
      $endgroup$
      – Chester Miller
      yesterday






    • 1




      $begingroup$
      In my experience people mess up the differentiation and then think they did everything wrong
      $endgroup$
      – Charlie Crown
      yesterday






    • 2




      $begingroup$
      Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
      $endgroup$
      – orthocresol
      yesterday












    • $begingroup$
      @orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
      $endgroup$
      – Mithoron
      yesterday






    • 2




      $begingroup$
      No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
      $endgroup$
      – Charlie Crown
      yesterday


















    • $begingroup$
      I don't think you should basically have revealed the full solution.
      $endgroup$
      – Chester Miller
      yesterday






    • 1




      $begingroup$
      In my experience people mess up the differentiation and then think they did everything wrong
      $endgroup$
      – Charlie Crown
      yesterday






    • 2




      $begingroup$
      Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
      $endgroup$
      – orthocresol
      yesterday












    • $begingroup$
      @orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
      $endgroup$
      – Mithoron
      yesterday






    • 2




      $begingroup$
      No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
      $endgroup$
      – Charlie Crown
      yesterday
















    $begingroup$
    I don't think you should basically have revealed the full solution.
    $endgroup$
    – Chester Miller
    yesterday




    $begingroup$
    I don't think you should basically have revealed the full solution.
    $endgroup$
    – Chester Miller
    yesterday




    1




    1




    $begingroup$
    In my experience people mess up the differentiation and then think they did everything wrong
    $endgroup$
    – Charlie Crown
    yesterday




    $begingroup$
    In my experience people mess up the differentiation and then think they did everything wrong
    $endgroup$
    – Charlie Crown
    yesterday




    2




    2




    $begingroup$
    Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
    $endgroup$
    – orthocresol
    yesterday






    $begingroup$
    Full solutions are fine! We encourage them: chemistry.meta.stackexchange.com/questions/4287/…
    $endgroup$
    – orthocresol
    yesterday














    $begingroup$
    @orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
    $endgroup$
    – Mithoron
    yesterday




    $begingroup$
    @orthocresol Well, in this case it's rather there shouldn't be an answer as I don't see how this question wouldn't violate HW policy.
    $endgroup$
    – Mithoron
    yesterday




    2




    2




    $begingroup$
    No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
    $endgroup$
    – Charlie Crown
    yesterday




    $begingroup$
    No way around it being a Homework question, but I answered it because there was a time when I had the same question. I tried to provide a means for understanding the solution. The final answer is not that important, but the concept... I hope I showed the concept. If I did, then it is a worthwhile question to have, and solution to have.
    $endgroup$
    – Charlie Crown
    yesterday











    7












    $begingroup$

    For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
    $$
    text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
    $$



    To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.



    For the case given:



    $$
    mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
    $$



    If $mathrm dp$ is an exact differential, that would mean that:



    $$
    left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
    $$



    There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.



    Integration



    Taking indefinite integrals of the suspected derivatives:



    $$int frac RV mathrm d T = frac{RT}{V} + g(V) \
    int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
    to p(T,V) = frac{RT-2a}{V} + c
    $$



    Differentiation



    It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:



    $$
    frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
    $$



    Assuming:
    $$ left(frac{partial p}{partial T}right)_{V} = frac RV \
    to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
    $$



    Assuming



    $$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
    to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
    $$



    Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.






    share|improve this answer











    $endgroup$


















      7












      $begingroup$

      For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
      $$
      text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
      $$



      To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.



      For the case given:



      $$
      mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
      $$



      If $mathrm dp$ is an exact differential, that would mean that:



      $$
      left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
      $$



      There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.



      Integration



      Taking indefinite integrals of the suspected derivatives:



      $$int frac RV mathrm d T = frac{RT}{V} + g(V) \
      int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
      to p(T,V) = frac{RT-2a}{V} + c
      $$



      Differentiation



      It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:



      $$
      frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
      $$



      Assuming:
      $$ left(frac{partial p}{partial T}right)_{V} = frac RV \
      to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
      $$



      Assuming



      $$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
      to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
      $$



      Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.






      share|improve this answer











      $endgroup$
















        7












        7








        7





        $begingroup$

        For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
        $$
        text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
        $$



        To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.



        For the case given:



        $$
        mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
        $$



        If $mathrm dp$ is an exact differential, that would mean that:



        $$
        left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
        $$



        There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.



        Integration



        Taking indefinite integrals of the suspected derivatives:



        $$int frac RV mathrm d T = frac{RT}{V} + g(V) \
        int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
        to p(T,V) = frac{RT-2a}{V} + c
        $$



        Differentiation



        It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:



        $$
        frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
        $$



        Assuming:
        $$ left(frac{partial p}{partial T}right)_{V} = frac RV \
        to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
        $$



        Assuming



        $$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
        to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
        $$



        Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.






        share|improve this answer











        $endgroup$



        For a given function, $F(x,y,z,...)$, it's differential $text{d}F$ is given by:
        $$
        text{d}F = left(frac{partial F}{partial x}right)_{y,z} text d x +left(frac{partial F}{partial y}right)_{x,z} text d y + left(frac{partial F}{partial z}right)_{x,y} text d z +; ...
        $$



        To say that a differential is an exact differential is to say that is if the differential of a function and hence is of the form given about.



        For the case given:



        $$
        mathrm dp(T,V)=frac RV,mathrm dT+left(frac{2a}{V^2}-frac{RT}{V^2}right),mathrm dV
        $$



        If $mathrm dp$ is an exact differential, that would mean that:



        $$
        left(frac{partial p}{partial T}right)_{V} = frac RV text{and } left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right)
        $$



        There are two equivalent way to determine whether this is true, you can integrate the partial derivatives of $p$ to recover a form for $p$, or you can differentiate each term once more to so that both give identical values for the mixed second derivative.



        Integration



        Taking indefinite integrals of the suspected derivatives:



        $$int frac RV mathrm d T = frac{RT}{V} + g(V) \
        int left(frac{2a}{V^2}-frac{RT}{V^2}right) mathrm d V = frac{-2a+RT}{V} + h(T) \
        to p(T,V) = frac{RT-2a}{V} + c
        $$



        Differentiation



        It is typically easier to compare the suspected derivative by differentiation. If $p$ is a true function of $T$ and $V$, by the symmetry of mixed derivatives:



        $$
        frac{partial }{partial T }_V left(frac{partial p }{partial V }right)_T = frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V
        $$



        Assuming:
        $$ left(frac{partial p}{partial T}right)_{V} = frac RV \
        to frac{partial }{partial V }_T left( frac{partial p }{partial T } right)_V = -frac{R}{V^2}
        $$



        Assuming



        $$ left(frac{partial p}{partial V}right)_{T} = left(frac{2a}{V^2}-frac{RT}{V^2}right) \
        to frac{partial }{partial T }_V left( frac{partial p }{partial V } right)_T = -frac{R}{V^2}
        $$



        Both terms of the differential $mathrm dp$ imply the same mixed second derivative, hence $mathrm dp$ is an exact differential.







        share|improve this answer














        share|improve this answer



        share|improve this answer








        edited 4 hours ago









        Tyberius

        7,00832160




        7,00832160










        answered yesterday









        user213305user213305

        1,031416




        1,031416






























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